The Japan Academy

Personal Information

 

Name

TATSUMI Kazuyuki

 

Section

Section II, Fourth Subsection

Date of Election

2014/12/12

Speciality

Inorganic Chemistry

Selected Bibliography

  1. Synthesis of the P-Cluster Inorganic Core of Nitrogenases. Y. Ohki, Y. Sunada, M. Honda, M. Katada, and K. Tatsumi, J. Am. Chem. Soc., 125, 4052-4053 (2003).
  2. Dithiolato-Bridged Dinuclear Iron-Nickel Complexes [Fe(CO)2(CN)2(μ-SCH2CH2CH2S)Ni (S2CNR2)]- Modeling the Active Site of [NiFe] Hydrogenase. Z. Li, Y. Ohki, and K. Tatsumi, J. Am. Chem. Soc., 127, 8950-8951 (2005).
  3. Synthesis of New [8Fe-7S] Clusters: A Topological Link Between the Core Structures of P-Cluster, FeMo-co, and FeFe-co of Nitrogenases. Y. Ohki, Y. Ikagawa, and K. Tatsumi, J. Am. Chem. Soc., 129, 10457-10465 (2007).
  4. Thiolate-Bridged Dinuclear Iron(tris-Carbonyl)-Nickel Complexes Relevant to the Active Site of [NiFe] Hydrogenase. Y. Ohki, K. Yasumura, K. Kuge, S. Tanino, M. Ando, Z. Li, and K. Tatsumi, Proc. Nat. Acad. Sci. U.S.A., 105, 7652-7657 (2008).
  5. Reversible Heterolysis of H2 Mediated by an M-S(thiolate) Bond (M = Ir, Rh): A Mechanistic Implication for [NiFe] Hydrogenase. Y. Ohki, M. Sakamoto, and K. Tatsumi, J. Am. Chem. Soc., 130, 11610-11611 (2008).
  6. Dinuclear Nickel Complexes Modeling the Structure and Function of the Acetyl CoA Synthase Active Site. M. Ito, M. Kotera, T. Matsumoto, and K. Tatsumi, Proc. Nat. Acad. Sci. U.S.A., 106, 11862-11866 (2009).
  7. Synthesis, Structures, and Electronic Properties of [8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster. Y. Ohki, M. Imada, A. Murata, Y. Sunada, S. Ohta, M. Honda, T. Sasamori, N. Tokitoh, M. Katada, and K. Tatsumi, J. Am. Chem. Soc., 131, 13168-13178 (2009).
  8. Host Plant Genome Overcomes the Lack of a Bacterial Gene for Symbiotic Nitrogen Fixation. T. Hakoyama, K. Niimi, H. Watanabe, R. Tabata, J. Matsubara, S. Sato, Y. Nakamura, S. Tabata, L. Jichun, T. Matsumoto, K. Tatsumi, M. Nomura, S. Tajima, M. Ishizaka, K. Yano, H. Imaizumi-Anraku, M. Kawaguchi, H. Kouchi, and N. Suganuma, Nature, 462, 514-517 (2009).
  9. A Model for the CO-Inhibited Form of [NiFe] Hydrogenase: Synthesis of (CO)3Fe(μ-StBu)3Ni {SC6H3-2,6-(mesityl)2} and Reversible CO Addition at the Ni Site. Y. Ohki, K. Yasumura, M. Ando, S. Shimokata, and K. Tatsumi, Proc. Nat. Acad. Sci. U.S.A., 107, 3994-3997 (2010).
  10. Synthetic Analogues of [Fe4S4(Cys)3(His)] in Hydrogenases and [Fe4S4(Cys)4] in HiPIP Derived from All-Ferric [Fe4S4{N(SiMe3)2}4]. Y. Ohki, K. Tanifuji, N. Yamada, M. Imada, T. Tajima, and K. Tatsumi, Proc. Nat. Acad. Sci. U.S.A., 108, 12635-12640 (2011).
  11. [3:1] Site-Diffentiated [4Fe-4S] Clusters Having One Carboxylate and Three Thiolates. T. Terada, K. Hirabayashi, D. Liu, T. Nakamura, T. Wakimoto, T. Matsumoto, and K. Tatsumi, Inorg. Chem. 52, 11997-12004 (2013).
  12. Combining a Nitrogenase Scaffold and a Synthetic Compound into an Artificial Enzyme. K. Tanifuji, C. C. Lee, Y. Ohki, K. Tatsumi, Y. L. Hu, M. W. Ribbe, Angew. Chem. Int. Ed., 54, 14022-14025 (2015).
  13. Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor. K. Tanifuji, N. Sickerman, C. C. Lee, T. Nagasawa, K. Miyazaki, Y. Ohki, K. Tatsumi, Y. Hu, M. W. Ribbe, Angew. Chem. Int. Ed., 55, 15633-15636 (2016).
  14. Reduction of C1 Sudstrates to Hydrocarbons by the Homometallic Precursor and Synthetic Mimic of the Nitrogenase Cofactor. N. S. Sickerman, K. Tanifuji, Y. Ohki, K. Tatsumi, M. W. Ribbe, Y. Hu, J. Am. Chem. Soc., 139, 603-606 (2017).
  15. Tracing the ‘Ninth Sulfur’ of Nitrogenase Cofactor via a Semi-Synthetic Approach. K. Tanifuji, C. C. Lee, N. S. Sickerman, K. Tatsumi, Y. Ohki, Y. Hu, M. W. Ribbe, Nat. Chem., 10, 568-567 (2018)
  16. Synthesis of an All-Ferric Cuboidal Cluster [FeIII4S4(SAr)4]. G. Moula, T. Matsumoto, M. E. Miehlich, K. Meyer, K. Tatsumi, Angew. Chem. Int. Ed., 57, 11594-11597 (2018).
  17. A Dithiolato and Hydrido Bridged (CO/CN)Fe-Ni Complex with Unprotected CN: A Model for the [Ni-R] State of the [Ni-Fe] Hydrogenase Active Site.    M. Bose, Z.-L. Li, T. Matsumoto, K. Tatsumi, Inorg. Chem., 59, 968-971 (2020).
  18. Synthesis of a Nitrogenase PN-Cluster Model with [Fe8S7(m-Sthiolate)2] Core from the All-Ferric [Fe4S4(Sthiolate)4] Cubane Synthon. G. Moula, A. Nagasaki, T. Matsumoto, M. E. Miehlich, K. Meyer, R. E. Cramer, K. Tatsumi, Angew. Chem. Int. Ed., 60, 15792-15797 (2021).